“碳?xì)滏I活化是有機(jī)化學(xué)中的圣杯”，
這句話曾經(jīng)被多位有機(jī)化學(xué)的專家學(xué)者提及，且近年來(lái)，C-H活化文章屢屢登上Science[1][2] 和Nature[3]足以證明此反應(yīng)在有機(jī)化學(xué)中的重要性。 百靈威緊跟科研熱點(diǎn)，推出C-H活化試劑，助力科研工作。
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產(chǎn)品編號(hào)
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產(chǎn)品名稱
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CAS
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結(jié)構(gòu)式
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包裝
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725455
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Tetrakis(triphenylacetato)
dirhodium(II)
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142214-04-8
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.PNG)
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100mg
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662623
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Bis[rhodium(α,α,α′,α′-
tetramethyl-1,3-benzenedipropionic acid)]
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819050-89-0
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.PNG)
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100mg
500mg
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684821
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1,2-Bis(phenylsulfinyl)
ethane palladium(II)
acetate
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858971-43-4
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.PNG)
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1g
250mg
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471143
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Tetrakis[1-[[4-alkyl(C11-C13)phenyl]sulfonyl]-
(2R)-pyrrolidinecarboxylate]
dirhodium(II)
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N/A
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N/A
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250mg
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175583
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Tris(triphenylphosphine)
rhodium(I) chloride
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14694-95-2
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.png)
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1g
5g
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參考文獻(xiàn)：
[1] Jeffrey J L, Terrett J A, MacMillan D W C. O–H hydrogen bonding promotes H-atom transfer from α C–H bonds for C-alkylation of alcohols[J]. Science, 2015, 349(6255): 1532-1536.
[2] Chen G, Gong W, Zhuang Z, et al. Ligand-accelerated enantioselective methylene C (sp3)–H bond activation[J]. Science, 2016, 353(6303): 1023-1027.
[3] ZHANG Z, TAMAKA K, YU J Q.Remote site-selective C–H activation directed by a catalytic bifunctional template[J]. Nature, 2017, 543: 538-542.